Structural transformation mediated by o-, m-, and p-phthalates from two to three dimensions for manganese/phthalate/4,4 '-bpy complexes (4,4 '-bpy=4,4 '-bipyridine)
2003 (English)In: New Journal of Chemistry, ISSN 1144-0546, E-ISSN 1369-9261, Vol. 27, no 5, 890-894 p.Article in journal (Refereed) Published
Three isomers of o-, m-, and p-phthalate are used to link together Mn centres, resulting in [Mn(phth)(H2O)(x)](n) moieties ( phth = phthalate dianion) with single-chain, double-chain and sheet structures, respectively, which predetermine the extended structures derived from the crosslinkage of 4,4'-bipyridine, and show the influence of isomerism of the phthalate on topological changes of the final polymers from two dimensional (2D) single-layer, double-layer to 3D network architectures. These structural changes in topology are correlated with the differences in the magnetic and optical properties of the polymers.
Place, publisher, year, edition, pages
2003. Vol. 27, no 5, 890-894 p.
metal-organic framework, coordination polymer, magnetic-properties, crystal-structure, hydrothermal synthesis, building-blocks, porous solids, chemistry, 4,4'-bipyridine, cavities
IdentifiersURN: urn:nbn:se:kth:diva-22460ISI: 000182568700024OAI: oai:DiVA.org:kth-22460DiVA: diva2:341158
QC 201005252010-08-102010-08-10Bibliographically approved