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Stereoselective aza-Diels-Alder reactions with 2H-azirines as dienophiles furnishing highly functionalized tetrahydropyridines
KTH, Superseded Departments, Chemistry.
KTH, Superseded Departments, Chemistry.
2003 (English)In: Chemical Communications, ISSN 1359-7345, E-ISSN 1364-548X, no 10, 1150-1151 p.Article in journal (Refereed) Published
Abstract [en]

Highly diastereoselective Lewis acid mediated aza-Diels-Alder reactions of chiral auxiliary derivatized 2H-azirines have been accomplished for the first time, yielding bi and tricyclic heterocyclic compounds, comprising aziridine and tetrahydropyridine substructures, in up to 97% de; with the absolute stereochemistry of the major product confirmed by X-ray crystallography.

Place, publisher, year, edition, pages
2003. no 10, 1150-1151 p.
Keyword [en]
diastereoselective synthesis, cycloadditions
URN: urn:nbn:se:kth:diva-22461DOI: 10.1039/b300849eISI: 000182569100017OAI: diva2:341159
QC 20100525Available from: 2010-08-10 Created: 2010-08-10Bibliographically approved

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Fischer, AndreasSomfai, Peter
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