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Migration and emission of plasticizer and its degradation products during thermal aging of nitrite rubber
KTH, Superseded Departments, Polymer Technology.ORCID iD: 0000-0002-7790-8987
KTH, Superseded Departments, Polymer Technology.
KTH, Superseded Departments, Polymer Technology.ORCID iD: 0000-0002-5394-7850
2003 (English)In: IJPAC. International journal of polymer analysis and characterization, ISSN 1023-666X, E-ISSN 1563-5341, Vol. 8, no 4, 279-293 p.Article in journal (Refereed) Published
Abstract [en]

The behavior of nitrile rubber during long-term thermal aging was evaluated by following the migration of low-molecular-weight additives and additive degradation products from the material. Headspace-GC-MS analysis showed that at 60degreesC the number of low-molecular-weight compounds released was rather low, but a significant increase in the number and amount of products was observed when the temperature was raised from 60degrees to 80degreesC, e.g., several degradation products of tris(2-butoxyethyl)phosphate plasticizer including 2-butoxyethanol and 1-butanol were identified. Oxidation of the plasticizer was also seen in the FTIR spectra. The color of the material changed from light brown to almost black during the aging.

Place, publisher, year, edition, pages
2003. Vol. 8, no 4, 279-293 p.
Keyword [en]
nitrile rubber, thermal aging, polymer degradation, plasticizer decomposition, acrylonitrile-butadiene copolymer, solid-phase microextraction, polyacrylonitrile, thermooxidation, photooxidation, spectrometry, oxidation, mechanism, air
National Category
Polymer Technologies Polymer Chemistry
Identifiers
URN: urn:nbn:se:kth:diva-22640DOI: 10.1080/10236660304883ISI: 000183944500005OAI: oai:DiVA.org:kth-22640DiVA: diva2:341338
Note
QC 20100525 NR 20140804Available from: 2010-08-10 Created: 2010-08-10 Last updated: 2017-12-12Bibliographically approved

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Hakkarainen, MinnaKarlsson, Sigbritt

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