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Application of bis-sulfonamides in asymmetric catalysis. Addition of diethylzinc to prochiral aldehydes
KTH, Superseded Departments, Chemistry.ORCID iD: 0000-0002-1743-7650
2003 (English)In: Russian journal of organic chemistry, ISSN 1070-4280, E-ISSN 1608-3393, Vol. 39, no 3, 436-452 p.Article, review/survey (Refereed) Published
Abstract [en]

The review summarizes the authors' and published data on the Ti(OPr-i)(4)-catalyzed addition of diethylzinc to prochiral aldehydes in the presence of bis-sulfonamides. The effect of bis-sulfonamide structure and other factors on the enantioselectivity of formation of secondary alcohols is discussed.

Place, publisher, year, edition, pages
2003. Vol. 39, no 3, 436-452 p.
Keyword [en]
highly enantioselective addition, disulfonamide-ti(o-iso-pr)4-dialkyl zinc system, bis(sulfonamido) bis(amide) complexes, functionalized secondary alcohols, diels-alder cycloadditions, chiral titanate complexes, ti-mediated addition, o hydrogen-bond, allylic alcohols, titanium complexes
URN: urn:nbn:se:kth:diva-22675ISI: 000184207900018OAI: diva2:341373
QC 20100525Available from: 2010-08-10 Created: 2010-08-10Bibliographically approved

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