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Electrospray ionization mass spectrometry of rhenium(I) bipyridyl complexes
2003 (Chinese)In: Youji huaxue, ISSN 0253-2786, Vol. 23, no 10, p. 1135-1138Article in journal (Refereed) Published
Abstract [zh]

The electrospray ionization mass spectrometry (ESI-MS) of a series of rhenium(I) bipyridyl complexes [(4,4'-(COOEt)(2)-bPY)Re(CO)(3)RPF6], where bpy is 2,2'-bipyridine and R is pyridine, 4-methylpyridine, 4-hydroxypyridine, 4-aminopyridine or 10-(4-picolyl)phenothiazine (py-PTZ) was studied. The dissociation of the ligands (R) forms the fragment of [(4, 4'-( COOEt)(2)-bpy) Re (CO)3](+) at different voltages of in-source collision induced dissociation (CID). The dissociation tendency is in an order: pyridine > 4-methylpyridine > 4-hydroxypyridine > 4-aminopyridine > py-PTZ. It might be used to deduce the stability of these complexes when they are used as photosensitizers in solar cells.

Place, publisher, year, edition, pages
2003. Vol. 23, no 10, p. 1135-1138
Keyword [zh]
ESI-MS, in-source CID, rhenium(I) bipyridyl complex, photosensitive dye, light
Identifiers
URN: urn:nbn:se:kth:diva-22943ISI: 000186447800015OAI: oai:DiVA.org:kth-22943DiVA, id: diva2:341641
Note
QC 20100525Available from: 2010-08-10 Created: 2010-08-10 Last updated: 2017-12-12Bibliographically approved

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