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New representative of Bi-9(5+)-containing phases: synthesis and crystal structure of the Nb-IV-containing Bi10Nb3Cl18 compound
KTH, Superseded Departments, Chemistry.
2003 (English)In: Russian chemical bulletin, ISSN 1066-5285, E-ISSN 1573-9171, Vol. 52, no 10, 2100-2104 p.Article in journal (Refereed) Published
Abstract [en]

The Bi10Nb3Cl18 compound was prepared using the high-temperature ampoule method, and its crystal structure was determined by sing-le-crystal X-ray diffraction. This phase contains the Bi-9(5+) cluster polycations and Bi+ cations surrounded by the NbCl62- complex anions. The latter contain the paramagnetic central Nb-IV ions, as evidenced by magnetic measurements.

Place, publisher, year, edition, pages
2003. Vol. 52, no 10, 2100-2104 p.
Keyword [en]
clusters, bismuth polycations, subhalides, cluster
Identifiers
URN: urn:nbn:se:kth:diva-23100ISI: 000188261500003OAI: oai:DiVA.org:kth-23100DiVA: diva2:341798
Note
QC 20100525Available from: 2010-08-10 Created: 2010-08-10 Last updated: 2017-12-12Bibliographically approved

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