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Reaction between palladium(II) and gallium(III) halogenides in arenes: influence of halogen nature on the formation of binuclear palladium(I) clusters
KTH, Superseded Departments, Chemistry.
KTH, Superseded Departments, Chemistry.
KTH, Superseded Departments, Chemistry.
2004 (English)In: Journal of Organometallic Chemistry, ISSN 0022-328X, E-ISSN 1872-8561, Vol. 689, no 2, 489-492 p.Article in journal (Refereed) Published
Abstract [en]

Palladium(II) bromide reacts with gallium(III) bromide in the presence of arenes yielding binuclear palladium(l) complexes [Pd-2(GaBr4)(2)(arene)(2)], where arene = benzene (1), toluene (2) and p-xylene (3). Reaction of palladium(II) chloride with gallium(III) chloride in p-xylene leads to the analogous palladium(l) compound [Pd-2(GaCl4)(2)(p-xylene)(2)] (4); the X-ray structures of 1-4 were determined.

Place, publisher, year, edition, pages
2004. Vol. 689, no 2, 489-492 p.
Keyword [en]
palladium, gallium halogenides, binuclear complexes, crystal structures, catalyzed carbonylation, carbon-monoxide, complexes, reduction, colloids, bonds
National Category
Chemical Sciences
URN: urn:nbn:se:kth:diva-23130DOI: 10.1016/j.jorganchem.2003.10.033ISI: 000188598000029ScopusID: 2-s2.0-0347653163OAI: diva2:341828
QC 20100525 QC 20111031Available from: 2010-08-10 Created: 2010-08-10 Last updated: 2011-10-31Bibliographically approved

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