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A tridentate ligand for preparation of bisterpyridine-like ruthenium(II) complexes with an increased excited state lifetime
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2004 (English)In: Inorganic Chemistry Communications, ISSN 1387-7003, E-ISSN 1879-0259, Vol. 7, no 3, 337-340 p.Article in journal (Refereed) Published
Abstract [en]

A new tridentate polypyridine ligand, 6-(2-picolyl)-2,2'-bipyridine, as well as its homoleptic Ru(II) complex has been prepared. Photophysical studies show a prolonged lifetime of the excited state compared to [Ru(tpy)2](2+), where tpy is 2,2':6',2-terpyridine.

Place, publisher, year, edition, pages
2004. Vol. 7, no 3, 337-340 p.
Keyword [en]
ruthenium modified terpyridine complex, excited state lifetime, room-temperature luminescence, photosensitized supramolecular architectures, photoinduced electron-transfer, photosubstitution reactions, artificial photosynthesis, tris-bipyridine, photosystem-ii, absorption, chemistry, oxidation
URN: urn:nbn:se:kth:diva-23203ISI: 000189229800006OAI: diva2:341901
QC 20100525Available from: 2010-08-10 Created: 2010-08-10Bibliographically approved

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