Molybdenum-catalyzed asymmetric allylic alkylations
2004 (English)In: Accounts of Chemical Research, ISSN 0001-4842, E-ISSN 1520-4898, Vol. 37, no 3, 159-167 p.Article in journal (Refereed) Published
The highly regio- and enantioselective molybdenum-catalyzed allylic alkylation reaction has become a powerful synthetic tool during the past few years. This Account describes the achievements gained so far in the area, with special attention directed to the different chiral ligands that have been used for inducing chirality in the products, the range of allylic substrates and nucleophiles employed, mechanistic studies, and applications of the reaction in asymmetric syntheses.
Place, publisher, year, edition, pages
2004. Vol. 37, no 3, 159-167 p.
fast chemistry, c-c, substitution, ligands, complexes, acetates, stereoselectivity, cyclopropanation, coordination, example
IdentifiersURN: urn:nbn:se:kth:diva-23262DOI: 10.1021/ar030239vISI: 000220210100003ScopusID: 2-s2.0-1642397473OAI: oai:DiVA.org:kth-23262DiVA: diva2:341960
QC 20100525 QC 201111012010-08-102010-08-102011-11-01Bibliographically approved