Synthesis of two novel rhenium(I) bipyridyl photosensitive dyes
2004 (English)In: Chinese Chemical Letters, ISSN 1001-8417, Vol. 15, no 8, 965-968 p.Article in journal (Refereed) Published
Two novel rhenium(I) 2, 2'-bipyridyl complexes, [(4,4'-di-COOEt-bipy) Re(CO)3 (NCCH3)PF6] and [(4,4'-di-COOEt-bipy) Re (CO)(3) (NCS)], a model complex [(4,4'-di-COOEt-bipy) Re (CO)(3) (pyridine)PF6], were synthesized. Their ground state electronic spectra and emission spectra were measured in acetonitrile. The MLCT absorption maximum of the complex exhibited a considerable red shift as the ligand changed from pyridine to CNCH3, or SCN.
Place, publisher, year, edition, pages
2004. Vol. 15, no 8, 965-968 p.
Rhenium(I) 2, 2 '-bipyridyl complex, photosensitizer, red shift, tio2 electrodes, complexes
IdentifiersURN: urn:nbn:se:kth:diva-23647ISI: 000223287000024OAI: oai:DiVA.org:kth-23647DiVA: diva2:342346
QC 201005252010-08-102010-08-10Bibliographically approved