Change search
ReferencesLink to record
Permanent link

Direct link
Crystal structure and electrochemical behavior of copper complex with 6-hydroxymethyl-substituted tris(2-pyridylmethyl) amine, CuCl(C19H20N4O) ClO4
Show others and affiliations
2004 (English)In: Jiégòu huàxué, ISSN 0254-5861, Vol. 23, no 11, 1262-1265 p.Article in journal (Refereed) Published
Abstract [en]

A Cu(II) complex [CuCl(C19H20N40)]ClO4 1 containing hydroxymethyl substituted TPA (TPA = tris(2-pyridylmethyl)amine) was prepared. It crystallizes in monoclinic, space group P2(1)/c with a = 11.7628(2), b = 13.0083(3), c = 15.11280(10) Angstrom, beta = 108.724(2)degrees, V = 2190.09(7) Angstrom(3), M-r = 518.83, Z = 4, T = 293 (2) K, D-c = 1.574 g/cm(3), mu = 1.280 mm(-1), F(000) = 1060 and S = 1.085. The final R = 0.0543 and wR = 0.1433 for 2693 observed reflections with I >2sigma(I). The penta-coordinated copper (H) complex. assumes an approximate square pyramidal geometry. Cyclic voltammetry measurement of the complex showed a quasi-reversible Cu-II/Cu-I redox couple with E-1/2 -0.467 v and DeltaE = 68 mv.

Place, publisher, year, edition, pages
2004. Vol. 23, no 11, 1262-1265 p.
Keyword [en]
copper complex, substituted TPA, cyclic voltammetry, tripodal tetradentate ligand, cu(i) complex, dioxygen, adducts
URN: urn:nbn:se:kth:diva-23910ISI: 000225357800010OAI: diva2:342609
QC 20100525Available from: 2010-08-10 Created: 2010-08-10Bibliographically approved

Open Access in DiVA

No full text

In the same journal
Jiégòu huàxué

Search outside of DiVA

GoogleGoogle Scholar
The number of downloads is the sum of all downloads of full texts. It may include eg previous versions that are now no longer available

Total: 21 hits
ReferencesLink to record
Permanent link

Direct link