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NMR studies of surfactants
KTH, Superseded Departments, Chemistry.
KTH, Superseded Departments, Chemistry.
2004 (English)In: Concepts in magnetic resonance. Bridging education and research, ISSN 1546-6086, E-ISSN 1552-5023, Vol. 23A, no 2, 121-135 p.Article in journal (Refereed) Published
Abstract [en]

Surfactant molecules are amphipathic and posses complicated solution chemistry and self-assembly properties. In addition to being of enormous practical significance, the physical characterization of surfactant systems presents a rich area of condensed matter physics. This article focuses on the application and interpretation of the commonly used NMR approaches for probing these systems. In particular, the use of NMR relaxation, diffusometry and, more briefly, electrophoretic NMR to determine characteristics such as micellar size and structure, ion-binding and solubilization are considered. The application of these NMR techniques is illustrated by a number of pertinent examples.

Place, publisher, year, edition, pages
2004. Vol. 23A, no 2, 121-135 p.
Keyword [en]
surfactants, nanoscience, NMR diffusometry, diffusion, cmc, NMR relaxation, two-step model, micellar size, obstruction effects, ion-binding, solubilization, surfactantpolymer interactions, electrophoretic NMR, nuclear-magnetic-resonance, multicomponent self-diffusion, organic counterion binding, sodium dodecyl-sulfate, least-squares analysis, gradient spin-echo, studying translational diffusion, paramagnetic relaxation method, ionic micellar-solutions, cubic liquid-crystals
National Category
Chemical Sciences
URN: urn:nbn:se:kth:diva-23920DOI: 10.1002/cmr.a.20022ISI: 000225447700004OAI: diva2:342619
QC 20100525 QC 20110915Available from: 2010-08-10 Created: 2010-08-10 Last updated: 2011-09-15Bibliographically approved

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Stilbs, PeterPrice, William S.
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