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Synthesis of a Ru(bpy)(3)-type complex linked to a free terpyridine ligand and its use for preparation of polynuclear bimetallic complexes
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2004 (English)In: Catalysis Today, ISSN 0920-5861, E-ISSN 1873-4308, Vol. 98, no 4, 529-536 p.Article in journal (Refereed) Published
Abstract [en]

A terpyridine ligand has been covalently linked to a Ru(bpy)(3) complex via an amide bond. By using this functionalized terpyridine ligand, a series of multinuclear bimetallic complexes have been synthesized and characterized. One of these complexes has the structure of di-mu-oxobridged Mn dimer. EPR spectra of this complex showed that, depending on the procedure for the preparation, the oxidation states of the Mn dimer is either a Mn-2(III,IV) dimer or a mixture of this and Mn-2(IV,IV) dimer. Water oxidation catalyzed by this complex has been performed.

Place, publisher, year, edition, pages
2004. Vol. 98, no 4, 529-536 p.
Keyword [en]
water oxidation, artificial photosynthesis, photosystem II, ruthenium-manganese, electrochemistry, EPR, homogeneous catalysis, mononuclear manganese(iv) complexes, intramolecular electron-transfer, mixed-valence interactions, water oxidation, paramagnetic resonance, oxygen evolution, photosystem-ii, artificial photosynthesis, epr spectroscopy, frozen solutions
URN: urn:nbn:se:kth:diva-23969ISI: 000225911300011OAI: diva2:342668
QC 20100525Available from: 2010-08-10 Created: 2010-08-10Bibliographically approved

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