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On the standard Gibbs energy of formation of CoO
KTH, Superseded Departments, Materials Science and Engineering.
KTH, Superseded Departments, Materials Science and Engineering.
2004 (English)In: Scandinavian journal of metallurgy, ISSN 0371-0459, E-ISSN 1600-0692, Vol. 33, no 6, 305-309 p.Article in journal (Refereed) Published
Abstract [en]

The standard Gibbs energy of formation of CoO was determined by the galvanic cell (-) Pt, Fe(s), 'FeO'(s)//ZrO2 (partially stabilised//CoO(s), Co(s), Pt (+) with CaO or Y2O3) in the temperature range 1052-1488 K. The results are compared with earlier reported values. An equation for the standard Gibbs energy change for the reactions Co(s) + 1/2O(2)(g) = CoO(s) and Co(s) + (O) under bar (Co, fcc) = CoO(s) is recommended based on the present

Place, publisher, year, edition, pages
2004. Vol. 33, no 6, 305-309 p.
Keyword [en]
cobalt oxide, galvanic cell, solid electrolytes, thermodynamics, high-temperature equilibria, solid-state emf, thermodynamic assessment, galvanic cell, electrolytes, aluminate, silicates, systems, nio
National Category
Metallurgy and Metallic Materials
Identifiers
URN: urn:nbn:se:kth:diva-23974ISI: 000226001900001Scopus ID: 2-s2.0-10844268807OAI: oai:DiVA.org:kth-23974DiVA: diva2:342673
Note
QC 20100525 QC 20110922Available from: 2010-08-10 Created: 2010-08-10 Last updated: 2017-12-12Bibliographically approved

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