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An unexpectedly mild thermal alder-ene-type cyclization of enallenes
2006 (English)In: Journal of Organic Chemistry, ISSN 0022-3263, E-ISSN 1520-6904, Vol. 71, no 7, 2914-2917 p.Article in journal (Refereed) Published
Abstract [en]

A mild, thermal Alder-ene reaction of enallenes has been developed. The allenic double bond acts as the "ene" and generates a carbon-carbon bond to an unactivated olefinic "enophile" in DMF at 120 degrees C to give [n.3.0] bicyclic systems (n = 3-5) in good yields. Except for a minor [2 + 2] cycloaddition byproduct, the reaction proceeded with complete atom economy, as there is no requirement of a catalyst or additional reactants, and no waste products are formed in the process.

Place, publisher, year, edition, pages
2006. Vol. 71, no 7, 2914-2917 p.
Keyword [en]
Addition reactions, Byproducts, Catalysts, Chemical bonds, Chemical reactions, Wastes
National Category
Chemical Sciences
Identifiers
URN: urn:nbn:se:kth:diva-24254DOI: 10.1021/jo060013gISI: 000236652200053OAI: oai:DiVA.org:kth-24254DiVA: diva2:346056
Note
QC 20100830Available from: 2010-08-30 Created: 2010-08-30 Last updated: 2017-12-12Bibliographically approved

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Franzén, Johan

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