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Catalytic Chain-Breaking Pyridinol Antioxidants
KTH, School of Chemical Science and Engineering (CHE), Chemistry, Nuclear Chemistry.
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2008 (English)In: Organic Letters, ISSN 1523-7060, E-ISSN 1523-7052, Vol. 10, no 21, 4895-4898 p.Article in journal (Refereed) Published
Abstract [en]

When assayed for their capacity to inhibit azo-initiated peroxidation of linoleic acid in a water/chlorobenzene two-phase system, tellurium-containing 3-pyridinols were readily regenerable by N-acetylcysteine contained in the aqueous phase. The best inhibitors quenched peroxyl radicals more efficiently than alpha-tocopherol, and the duration of inhibition was limited only by the availability of the thiol reducing agent. The compounds were also found to catalyze reduction of hydrogen peroxide in the presence of thiol reducing agent.

Place, publisher, year, edition, pages
2008. Vol. 10, no 21, 4895-4898 p.
Keyword [en]
VITAMIN-E, ALPHA-TOCOPHEROL, SYNERGISTIC INHIBITION, OXIDATION, PEROXIDATION, ANALOGS, GLUTATHIONE, REACTIVITY, CHEMISTRY, LIPOSOMES
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Chemical Sciences
Identifiers
URN: urn:nbn:se:kth:diva-24342DOI: 10.1021/ol801983nISI: 000260534500047Scopus ID: 2-s2.0-60949083057OAI: oai:DiVA.org:kth-24342DiVA: diva2:346965
Note
QC 20100902Available from: 2010-09-02 Created: 2010-09-02 Last updated: 2017-12-12Bibliographically approved

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Jonsson, Mats

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