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Dual Lewis acid-Lewis base activation in enantioselective additions to aldehydes
KTH, School of Chemical Science and Engineering (CHE), Chemistry.
KTH, School of Chemical Science and Engineering (CHE), Chemistry.
KTH, School of Chemical Science and Engineering (CHE).
KTH, School of Chemical Science and Engineering (CHE), Chemistry, Organic Chemistry.ORCID iD: 0000-0002-1743-7650
2006 (English)In: Pure and Applied Chemistry, ISSN 0033-4545, E-ISSN 1365-3075, Vol. 78, no 2, 409-414 p.Article in journal (Refereed) Published
Abstract [en]

Reaction of benzaldehyde with ethyl cyanoformate in the presence of Lewis acidic Ti(IV) complexes of bispyridylamide or salen ligands and Lewis basic amines affords the O-alkoxycarbonylated cyanohydrin. In the presence of the salen-based catalytic system, acetyl cyanide can also be added to benzaldehyde, providing a highly enantioselective direct route to the O-acetylated cyanohydrin.

Place, publisher, year, edition, pages
2006. Vol. 78, no 2, 409-414 p.
Keyword [en]
Lewis base, Lewis acid, cyanohydrin, titanium, salen, bispyridylamide
National Category
Chemical Sciences
Identifiers
URN: urn:nbn:se:kth:diva-24437DOI: 10.1351/pac200678020409ISI: 000235784500026Scopus ID: 2-s2.0-33644539834OAI: oai:DiVA.org:kth-24437DiVA: diva2:349876
Note
QC 20100909. Conference: 13th IUPAC International Symposium on Organometallic Chemistry Directed Towards Organic Synthesis (OMCOS-13). Geneva, SWITZERLAND. JUL 17-21, 2005Available from: 2010-09-09 Created: 2010-09-09 Last updated: 2017-12-12Bibliographically approved

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Moberg, Christina

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Wingstrand, EricaLundgren, StinaPenhoat, MaëlMoberg, Christina
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