The effect of Zirconium Disilicide (ZrSi2) additions on the carbon oxidation behavior of alumina/Graphite refractory materials
2010 (English)In: ISIJ International, ISSN 0915-1559, Vol. 50, no 11, 1612-1621 p.Article in journal (Refereed) Published
Carbon oxidation is a main industrial problem for Alumina/Graphite Submerged Entry Nozzles (SEN) during pre-heating. Thus, the effect of ZrSi2 antioxidants and the coexistence of antioxidant additive and (4B2O3 ·BaO) glass powder on carbon oxidation were investigated at simulated non-isothermal heating conditions in a controlled atmosphere. Also, the effect of ZrSi2 antioxidants on carbon oxidation was investigated at isothermal temperatures at 1473 K and 1773 K. The specimens’ weight loss and temperature were plotted versus time and compared to each others. The thickness of the oxide areas were measured and examined using XRD, FEG-SEM and EDS. The coexistence of 8 wt% ZrSi2 and 15 wt% (4B2O3 ·BaO) glass powder of the total alumina/Graphite base refractory materials, presented the most effective resistance to carbon oxidation. The 121% volume expansion due to the Zircon formation during heating and filling up the open pores by (4B2O3 ·BaO) glaze during green body sintering led to an excellent carbon oxidation resistance.
Place, publisher, year, edition, pages
2010. Vol. 50, no 11, 1612-1621 p.
refractory, ZrSi2, graphite, alumina, oxidation
IdentifiersURN: urn:nbn:se:kth:diva-25097ISI: 000284967700013ScopusID: 2-s2.0-79551609986OAI: oai:DiVA.org:kth-25097DiVA: diva2:355760
Uppdaterad från manuskript till artikel(20110104).2010-10-082010-10-082011-10-14Bibliographically approved