Colloid diffusion in compacted bentonite: microstructural constraints
2010 (English)In: Clays and clay minerals, ISSN 0009-8604, Vol. 58, no 4, 532-541 p.Article in journal (Refereed) Published
In Sweden and in many other countries, a bentonite barrier will be used in the repository for spent nuclear fuel. In the event of canister failure, colloidal diffusion is a potential, but scarcely studied mechanism of radionuclide migration through the bentonite barrier. Column and in situ experiments are vital in understanding colloid diffusion and in providing information about the microstructure of compacted bentonite and identifying cut-off limits for colloid filtration. This study examined diffusion of negatively charged 2-, 5-, and 15-nm gold colloids in 4-month diffusion experiments using MX-80 Wyoming bentonite compacted to dry densities of 0.6–2.0 g/cm3. Breakthrough of gold colloids was not observed in any of the three diffusion experiments. In a gold-concentration profile analysis, colloid diffusion was only observed for the smallest gold colloids at the lowest dry density used (estimated apparent diffusivity Da 5x10–13 m2/s). The results from a microstructure investigation using low-angle X-ray diffraction suggest that at the lowest dry density used, interlayer transport of the smallest colloids cannot be ruled out as a potential diffusion pathway, in addition to the expected interparticle transport. In all other cases, with either greater dry densities or larger gold colloids, compacted bentonite will effectively prevent diffusion of negatively charged colloids due to filtration.
Place, publisher, year, edition, pages
2010. Vol. 58, no 4, 532-541 p.
Colloid Filtration • Compacted Bentonite, Gold Colloids, Diffusion, Microstructure, Nuclear Waste Disposal
IdentifiersURN: urn:nbn:se:kth:diva-25247DOI: 10.1346/CCMN.2010.0580408ISI: 000289446500008ScopusID: 2-s2.0-78149471771OAI: oai:DiVA.org:kth-25247DiVA: diva2:356746
QC 20101013. Tidigare titel: "Colloid Permeability of Compacted Bentonite: Microstructural Constraints".2010-10-132010-10-132011-06-08Bibliographically approved