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Photochemical H-2 production with noble-metal-free molecular devices comprising a porphyrin photosensitizer and a cobaloxime catalyst
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2010 (English)In: Chemical Communications, ISSN 1359-7345, E-ISSN 1364-548X, Vol. 46, no 46, 8806-8808 p.Article in journal (Refereed) Published
Abstract [en]

Among three noble-metal-free molecular devices (1-3) containing a porphyrin photosensitizer and a cobaloxime catalyst, the one with a zinc porphyrin unit displayed apparently higher efficiency for photoinduced H-2 production than complex 2 with a magnesium porphyrin and 3 with a free-base porphyrin, possibly due to the formation of a TEA center dot center dot center dot ZnPor-Co triad in solution.

Place, publisher, year, edition, pages
2010. Vol. 46, no 46, 8806-8808 p.
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Chemical Sciences
URN: urn:nbn:se:kth:diva-27095DOI: 10.1039/c0cc03154bISI: 000284229400032ScopusID: 2-s2.0-78549259159OAI: diva2:376041
QC 20101209Available from: 2010-12-09 Created: 2010-12-06 Last updated: 2010-12-09Bibliographically approved

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