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Synthesis and Characterization of Oligonuclear Ru, Co and Cu Oxidation Catalysts
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2010 (English)In: European Journal of Inorganic Chemistry, ISSN 1434-1948, E-ISSN 1099-1948, no 34, 5462-5470 p.Article in journal (Refereed) Published
Abstract [en]

In this work, we report the preparation and crystal structures of three new oligonuclear complexes, Ru-2(bbpmp)(mu-OAc)(3) (4), [Co-2(bbpmp)(mu-OAc)(mu-OMe)](PF6) (5), [Cu-4(Hbbpmp)(2)(mu-OAc)(H2O)(2)](OAc)(PF6)(2) (6) {H(3)bbpmp = 2,6-bis[(2-hydroxybenzyl)-(2-pyridylmethyl)aminomethyl]-4-methylphenol (3)}. The structures of the complexes were determined by single-crystal X-ray diffraction. The oxidation states of ruthenium, cobalt and copper in the complexes are +3, +3 and +2, respectively. In 4 and 5, Ru-III and Co-III are coordinated to four oxygen and two nitrogen atoms in an octahedral geometry, while in 6, Cu-II adopts both octahedral (CuN2O4) and square-pyramidal (CuN2O3) geometry. The potential of the three complexes as oxidation catalysts has been investigated.

Place, publisher, year, edition, pages
2010. no 34, 5462-5470 p.
Keyword [en]
O-O activation, Homogeneous catalysis, N, O ligands, Oxidation
National Category
Inorganic Chemistry
Identifiers
URN: urn:nbn:se:kth:diva-28599DOI: 10.1002/ejic.201000758ISI: 000285262900014Scopus ID: 2-s2.0-78649592886OAI: oai:DiVA.org:kth-28599DiVA: diva2:388080
Note
QC 20110117Available from: 2011-01-17 Created: 2011-01-17 Last updated: 2017-12-11Bibliographically approved

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