Change search
ReferencesLink to record
Permanent link

Direct link
Synthesis and Characterization of Oligonuclear Ru, Co and Cu Oxidation Catalysts
Show others and affiliations
2010 (English)In: European Journal of Inorganic Chemistry, ISSN 1434-1948, E-ISSN 1099-0682, no 34, 5462-5470 p.Article in journal (Refereed) Published
Abstract [en]

In this work, we report the preparation and crystal structures of three new oligonuclear complexes, Ru-2(bbpmp)(mu-OAc)(3) (4), [Co-2(bbpmp)(mu-OAc)(mu-OMe)](PF6) (5), [Cu-4(Hbbpmp)(2)(mu-OAc)(H2O)(2)](OAc)(PF6)(2) (6) {H(3)bbpmp = 2,6-bis[(2-hydroxybenzyl)-(2-pyridylmethyl)aminomethyl]-4-methylphenol (3)}. The structures of the complexes were determined by single-crystal X-ray diffraction. The oxidation states of ruthenium, cobalt and copper in the complexes are +3, +3 and +2, respectively. In 4 and 5, Ru-III and Co-III are coordinated to four oxygen and two nitrogen atoms in an octahedral geometry, while in 6, Cu-II adopts both octahedral (CuN2O4) and square-pyramidal (CuN2O3) geometry. The potential of the three complexes as oxidation catalysts has been investigated.

Place, publisher, year, edition, pages
2010. no 34, 5462-5470 p.
Keyword [en]
O-O activation, Homogeneous catalysis, N, O ligands, Oxidation
National Category
Inorganic Chemistry
URN: urn:nbn:se:kth:diva-28599DOI: 10.1002/ejic.201000758ISI: 000285262900014ScopusID: 2-s2.0-78649592886OAI: diva2:388080
QC 20110117Available from: 2011-01-17 Created: 2011-01-17 Last updated: 2011-01-17Bibliographically approved

Open Access in DiVA

No full text

Other links

Publisher's full textScopus

Search in DiVA

By author/editor
Xu, Yunhua
By organisation
In the same journal
European Journal of Inorganic Chemistry
Inorganic Chemistry

Search outside of DiVA

GoogleGoogle Scholar
The number of downloads is the sum of all downloads of full texts. It may include eg previous versions that are now no longer available

Altmetric score

Total: 24 hits
ReferencesLink to record
Permanent link

Direct link