Synthesis of Benzotriazine and Aryltriazene Derivatives Starting from 2-Azidobenzonitrile Derivatives
2010 (English)In: European Journal of Organic Chemistry, ISSN 1434-193X, E-ISSN 1099-0690, no 34, 6588-6599 p.Article in journal (Refereed) Published
3-Substituted 3,4-dihydro-4-imino-1,2,3-benzotriazine derivatives 7 were formed from 2-azidobenzonitriles 4 as starting materials on treatment with Grignard or lithium organic reagents. In some cases these procedures gave aryltriazenes 10 and 11 as products. All compounds were identified by NMR spectroscopy and the structures of three products, namely 7a, 10a and 11i, were corroborated by X-ray crystallography.
Place, publisher, year, edition, pages
2010. no 34, 6588-6599 p.
Nitrogen heterocycles, Grignard reaction, Substituent effects, Azides, Nitriles
IdentifiersURN: urn:nbn:se:kth:diva-28598DOI: 10.1002/ejoc.201000328ISI: 000285262700013ScopusID: 2-s2.0-78649533140OAI: oai:DiVA.org:kth-28598DiVA: diva2:388085
QC 201101172011-01-172011-01-172011-01-17Bibliographically approved