Change search
ReferencesLink to record
Permanent link

Direct link
Dynamic Kinetic Asymmetric Transformation (DYKAT) by Combined Amine- and Transition-Metal-Catalyzed Enantioselective Cycloisomerization
Show others and affiliations
2010 (English)In: Chemistry - A European Journal, ISSN 0947-6539, E-ISSN 1521-3765, Vol. 16, no 5, 1585-1591 p.Article in journal (Refereed) Published
Abstract [en]

The first examples of one-pot highly chemo- and enantioselective dynamic kinetic asymmetric transformations (DYKATs) involving alpha,beta-unsaturated aldehydes and proparaylated carbon acids are presented. These DYKATs, which proceed by a combination of catalytic iminium activation, enamine activation, and Pd-0-catalyzed enyne cycloisomerization, give access to functionalized cyclopentenes wit. It up to. 99% ee and can be used for the generation of all-carbon quaternary stereocenters

Place, publisher, year, edition, pages
2010. Vol. 16, no 5, 1585-1591 p.
Keyword [en]
asymmetric synthesis, cyclopentenes, dynamic kinetic transformation, organocatalysis, transition-metal catalysis
National Category
Chemical Sciences
URN: urn:nbn:se:kth:diva-28704DOI: 10.1002/chem.200902818ISI: 000275148500022ScopusID: 2-s2.0-75749086819OAI: diva2:390258
Swedish Research Council
QC 20110121Available from: 2011-01-21 Created: 2011-01-19 Last updated: 2011-01-21Bibliographically approved

Open Access in DiVA

No full text

Other links

Publisher's full textScopus

Search in DiVA

By author/editor
Zhang, Qiong
By organisation
Theoretical Chemistry
In the same journal
Chemistry - A European Journal
Chemical Sciences

Search outside of DiVA

GoogleGoogle Scholar
The number of downloads is the sum of all downloads of full texts. It may include eg previous versions that are now no longer available

Altmetric score

Total: 17 hits
ReferencesLink to record
Permanent link

Direct link