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Dynamic Kinetic Asymmetric Transformation (DYKAT) by Combined Amine- and Transition-Metal-Catalyzed Enantioselective Cycloisomerization
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2010 (English)In: Chemistry - A European Journal, ISSN 0947-6539, E-ISSN 1521-3765, Vol. 16, no 5, 1585-1591 p.Article in journal (Refereed) Published
Abstract [en]

The first examples of one-pot highly chemo- and enantioselective dynamic kinetic asymmetric transformations (DYKATs) involving alpha,beta-unsaturated aldehydes and proparaylated carbon acids are presented. These DYKATs, which proceed by a combination of catalytic iminium activation, enamine activation, and Pd-0-catalyzed enyne cycloisomerization, give access to functionalized cyclopentenes wit. It up to. 99% ee and can be used for the generation of all-carbon quaternary stereocenters

Place, publisher, year, edition, pages
2010. Vol. 16, no 5, 1585-1591 p.
Keyword [en]
asymmetric synthesis, cyclopentenes, dynamic kinetic transformation, organocatalysis, transition-metal catalysis
National Category
Chemical Sciences
Identifiers
URN: urn:nbn:se:kth:diva-28704DOI: 10.1002/chem.200902818ISI: 000275148500022Scopus ID: 2-s2.0-75749086819OAI: oai:DiVA.org:kth-28704DiVA: diva2:390258
Funder
Swedish Research Council
Note
QC 20110121Available from: 2011-01-21 Created: 2011-01-19 Last updated: 2017-12-11Bibliographically approved

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