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Organocatalytic Enantioselective Aziridination of alpha-Substituted alpha,beta-Unsaturated Aldehydes: Asymmetric Synthesis of Terminal Aziridines
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2010 (English)In: Advanced Synthesis and Catalysis, ISSN 1615-4150, E-ISSN 1615-4169, Vol. 352, no 18, 3201-3207 p.Article in journal (Refereed) Published
Abstract [en]

The first example of a highly enantioselective organocatalytic aziridination of alpha-substituted alpha,beta-unsaturated aldehydes is presented. The reaction is catalyzed by simple chiral amines and gives access to highly functional terminal azirdines containing an alpha-tertiary amine stereocenter in high yields and enantiomeric ratios (95.5:4.5-98:2).

Place, publisher, year, edition, pages
2010. Vol. 352, no 18, 3201-3207 p.
Keyword [en]
asymmetric catalysis, domino reactions, organocatalysis, alpha-substituted alpha, beta-unsaturated aldehydes, terminal aziridines
National Category
Theoretical Chemistry
URN: urn:nbn:se:kth:diva-30265DOI: 10.1002/adsc.201000650ISI: 000285397800019ScopusID: 2-s2.0-78650313899OAI: diva2:399252
Swedish Research Council
QC 20110221Available from: 2011-02-21 Created: 2011-02-21 Last updated: 2011-02-21Bibliographically approved

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Zhang, Qiong
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