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Dielectric Properties of Alumina-filled Poly (ethylene-co-butyl acrylate) Nanocomposites Part I - Dry Studies
KTH, School of Electrical Engineering (EES), Electromagnetic Engineering. (ETK)
KTH, School of Electrical Engineering (EES), Electromagnetic Engineering.
KTH, School of Chemical Science and Engineering (CHE), Fibre and Polymer Technology.
KTH, School of Chemical Science and Engineering (CHE), Fibre and Polymer Technology.
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2012 (English)In: IEEE transactions on dielectrics and electrical insulation, ISSN 1070-9878, E-ISSN 1558-4135, Vol. 19, no 2, 383-390 p.Article in journal (Refereed) Published
Abstract [en]

The dielectric properties of poly (ethylene-co-butyl acrylate) with 13 wt% of butyl acrylate (EBA) filled with alumina nanoparticles were studied as a function of particle size, particle coating, filler content (2, 6 or 12wt%) and temperature. The particles were either unmodified or surface-treated with either aminopropyltriethoxy silane or octyltriethoxy silane. The complex permittivity was measured with frequencies varying between 1 mHz and up to 1 kHz at different temperatures (25, 45 and 65 degrees C). Measurements were performed in dry conditions. From the dielectric spectroscopy measurements it can be seen that the tan delta for the dry samples is almost independent of the type of the particle coating used. It does, however, depend on the particle size, filler content and temperature.

Place, publisher, year, edition, pages
2012. Vol. 19, no 2, 383-390 p.
Keyword [en]
nanocomposite, nanofillers, alumina, poly(ethylene-co-butyl acrylate)
National Category
Other Electrical Engineering, Electronic Engineering, Information Engineering
Identifiers
URN: urn:nbn:se:kth:diva-31437DOI: 10.1109/TDEI.2012.6180229ISI: 000303069300002Scopus ID: 2-s2.0-84860176248OAI: oai:DiVA.org:kth-31437DiVA: diva2:403938
Note
QC 20120522Available from: 2011-03-15 Created: 2011-03-15 Last updated: 2017-12-11Bibliographically approved
In thesis
1. Dielectric properties of poly(ethyelene-co-butyl acrylate) filled with Alumina nanoparticles
Open this publication in new window or tab >>Dielectric properties of poly(ethyelene-co-butyl acrylate) filled with Alumina nanoparticles
2011 (English)Licentiate thesis, comprehensive summary (Other academic)
Abstract [en]

In this work dielectric properties of the poly(ethylene-co-butyl acrylate)filled with alumina nanoparticles are evaluated. These nanocomposite materialswere manufactured at the department of Fibre and Polymer Technology,KTH.This study is limited to the properties of general importance for the AC applications.The dielectric permittivity of the nanocomposite materials wasstudied as a function of filler size, filler content, coating, temperature and airhumidity used for conditioning of the samples. The ultimate goal with thisproject is to describe the influence of material composition, temperature andair humidity on the dielectric properties and model these dependencies.In this thesis the experimental setup for voltage endurance testing of thenanocomposites, namely studying applied voltage frequency dependence ofpartial discharges in electrical trees, with a possibility of following electricaltreeing optically, was developed and described.The dielectric spectroscopy measurements were performed on thoroughly driednanocomposites - so-called dry DS study. It was shown that the experimentaldata can be fitted with Havriliak-Negami approximation, which justifiesthe correctness of the measurement results. It has been shown that addingnanoparticles to the EBA matrix changes the low frequency dispersion significantlyfor the dried samples. It was also indicated that the particle coatingused has very low impact on the resulting permittivity of the thoroughly driedsamples. From the dry DS studies it was suggested that the main cause ofthe scattering in data between the dry samples is most likely the influenceof the material inhomogeneity and possibly the moisture absorption. Thisleads to a possibility of using dielectric spectroscopy as a tool for probing thedispersion of nanoparticles in the polymer matrix.The dielectric spectroscopy measurements were also carried out on the nanocompositesconditioned in the environments with different humidity levels of air inorder to study the influence of absorbed water on the dielectric permittivity- so-called wet DS study. From the wet study it was shown that for the wetsamples the amplitude of the loss peak is defined by the filler size, filler contentand coating used; while its position in frequency domain is determinedby the coating and the humidity level used for conditioning.

Place, publisher, year, edition, pages
Stockholm: KTH Royal Institute of Technology, 2011
Series
Trita-EE, ISSN 1653-5146 ; 2011:017
Keyword
nanocomposites, poly(ethylene-co-butyl acrylate), EBA, alumina, dielectric permittivity, absorbed water, humidity, temperature, dielectric spectroscopy, partial discharge, electrical treeing
National Category
Other Electrical Engineering, Electronic Engineering, Information Engineering
Identifiers
urn:nbn:se:kth:diva-31407 (URN)978-91-7415-900-4 (ISBN)
Presentation
2011-03-25, Seminarierummet, KTH, Teknikringen 33, Stockholm, 10:15 (English)
Opponent
Supervisors
Note
QC 20110315Available from: 2011-03-15 Created: 2011-03-14 Last updated: 2011-03-15Bibliographically approved
2. Electrical Insulating Properties of Poly(Ethylene-co-Butyl Acrylate) Filled with Alumina Nanoparticles
Open this publication in new window or tab >>Electrical Insulating Properties of Poly(Ethylene-co-Butyl Acrylate) Filled with Alumina Nanoparticles
2013 (English)Doctoral thesis, comprehensive summary (Other academic)
Abstract [en]

In this work the electrical insulating properties of the nanocomposite materials based on poly(ethylene-co-butyl acrylate) filled with alumina nanoparticles are studied. The dielectric properties chosen for the evaluation are the dielectric permittivity and loss as well as the breakdown strength and the pre-breakdown currents. The reason for choosing these particular properties is partly due to the importance of these for the general electrical applications and partly due to the uncertainties involved for these particular properties of the nanocomposite materials.

The importance of moisture absorption for the dielectric properties is outlined in this work. All measurements were performed in both dry conditions and after conditioning of the materials in humid environment until saturation. The data for moisture absorption was taken from the water absorption study performed at the Department of Fibre and Polymer Technology, KTH.

The dielectric spectroscopy in frequency domain was employed for measuring dielectric permittivity and loss. Havriliak-Negami approximation was used for characterization of the measurement data and at the same time ensuring the fulfillment of the Kramers-Kronig relations. Results from the dielectric spectroscopy study in dry conditions suggest that dielectric spectroscopy can be used for evaluating nanoparticle dispersion in the host matrix, based on correlation between the morphology data obtained from SEM investigation and the scatter in the dielectric loss. The dielectric spectroscopy study performed on the nanocomposites after conditioning in humid environment showed that absorbed moisture has a distinct impact on the dielectric loss. Especially pronounced is its’ influence on the frequency behavior, when the dielectric loss peaks are shifted towards higher frequencies with increased moisture content. The nanocomposite materials characterized by higher specific surface area generally exhibit higher dielectric losses. Surface functionalization of the nanoparticles does not seem to have much influence on the dielectric loss in dry conditions. After conditioning in humid environment, however, the surface modification was shown to have a significant impact. Temperature is another significant factor for the frequency behavior of the dielectric loss: it was found that the studied nanocomposites can be characterized by Arrhenius activation.

The breakdown strength and pre-breakdown currents study outlined the influence of moisture as well. The study indicated that surface treatment of the nanoparticles can enhance properties of the nanocomposite materials, namely aminopropyltriethoxy silane was an especially successful choice:

• The highest breakdown strength was determined by the study for NDA6 material formulation in dry conditions.

• After conditioning in humid environment the NDA6 material continued showing the best breakdown strength among the nanocomposite mate rials, as well as this value was close to the breakdown strength of the reference unfilled material.

This study confirms the existence of the optimal nanofiller content or rather optimal specific surface area of the dispersed nanoparticles in the host matrix. The latter is supported by the comparison between the nanocomposites based on nanoparticles with two different specific surface areas, which shows that the dielectric properties worsen, i.e. the dielectric losses increase and the influence of absorbed moisture on the breakdown strength becomes more pronounced, for nanomaterials with larger specific surface area. The pre-breakdown currents were found to follow space-charge limited conduction mechanism reasonably well. The following conduction regimes were identified: constant region (likely due to measurement difficulties at low field strengths), Ohm’s regime, trap-filled-limit regime and trapfree dielectric regime. The breakdown usually occurred either during the trap-filled-limit regime, when the current increased dramatically for the small change in electric field, or during the trapfree dielectric regime. The threshold values between different conduction regimes seem to correlate well with the oxidation induction times (OIT), which in turn depend on the total specific surface area. The pre-breakdown currents tend to be highest for the materials filled with the untreated nanoparticles. Increased absorbed moisture content causes higher pre-breakdown currents for the nanocomposite materials, while for the reference unfilled material the pre-breakdown currents do not show such tendency. Generally it can be said that the repeatability in the measured data is higher for the nanocomposite materials in comparison to the unfilled host material, as was demonstrated by both dielectric spectroscopy and breakdown studies.

Place, publisher, year, edition, pages
Stockholm: KTH Royal Institute of Technology, 2013. xii, 70 p.
Series
TRITA-EE, ISSN 1653-5146 ; 2013:005
Keyword
nanocomposites, poly(ethylene-co-butyl acrylate), EBA, alumina, dielectric permittivity, absorbed water, humidity, temperature, dielectric spectroscopy, breakdown strength, pre-breakdown current
National Category
Other Electrical Engineering, Electronic Engineering, Information Engineering
Identifiers
urn:nbn:se:kth:diva-116862 (URN)978-91-7501-647-4 (ISBN)
Public defence
2013-02-27, F3, Lindstetsvägen 26, KTH, Stockholm, 10:00 (English)
Opponent
Supervisors
Note

QC 20130207

Available from: 2013-02-07 Created: 2013-01-28 Last updated: 2014-02-11Bibliographically approved

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