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Interplay of covalent bonding and correlation effects at molecule-metal contacts
KTH, School of Industrial Engineering and Management (ITM), Materials Science and Engineering, Engineering Material Physics.
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2009 (English)In: Chemical Physics Letters, ISSN 0009-2614, E-ISSN 1873-4448, Vol. 478, no 4-6, 191-194 p.Article in journal (Refereed) Published
Abstract [en]

We compare photoelectron spectra (PES) and theoretical densities-of-states of C-60/Al(111), C-60/Al(110) and C-60/Al(100). The splitting observed on all three surfaces is attributed to final state charging. This splitting can also be used to improve estimates of the charging energy U of adsorbed molecules and as a criterion for the existence of strong covalent bonding to the electrode. Au exhibits weak bonding in available data, whereas Ag(100), with measurable charge transfer, appears qualitatively similar to Al.

Place, publisher, year, edition, pages
2009. Vol. 478, no 4-6, 191-194 p.
National Category
Physical Chemistry
URN: urn:nbn:se:kth:diva-32653DOI: 10.1016/j.cplett.2009.07.065ISI: 000269185000017ScopusID: 2-s2.0-68949178859OAI: diva2:411386
QC 20110418Available from: 2011-04-18 Created: 2011-04-18 Last updated: 2011-04-18Bibliographically approved

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Ahuja, Rajeev
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