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Synthesis of New Chiral Schiff Bases Containing Bromo- and Iodo-Functionalized Hydroxynaphthalene Frameworks
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2011 (English)In: Synthetic Communications, ISSN 0039-7911, E-ISSN 1532-2432, Vol. 41, no 9, 1381-1393 p.Article in journal (Refereed) Published
Abstract [en]

[image omitted] Two series of chiral Schiff bases 3a-g and 4a-g containing bromo- and iodo-functionalized hydroxynaphthalene frameworks were conveniently prepared in acceptable to moderate yields by controlled halogenation of hydroxynaphthaldehyde and then condensation of the corresponding mono-, di-, and trihalohydroxynaphthaldehyde with the chiral amino alcohol. Except for 4d, the Schiff bases 3a-g, 4a-c, and 4e-g prepared in the present work have not been reported in literature so far, and they might be used as effective chiral inducers in some asymmetrically synthetic reactions.

Place, publisher, year, edition, pages
2011. Vol. 41, no 9, 1381-1393 p.
Keyword [en]
Chiral schiff base, condensation, controlled halogenation, halohydroxynaphthaldehyde
National Category
Chemical Sciences
Identifiers
URN: urn:nbn:se:kth:diva-32590DOI: 10.1080/00397911.2010.486505ISI: 000288950300015Scopus ID: 2-s2.0-79953661193OAI: oai:DiVA.org:kth-32590DiVA: diva2:412182
Funder
Knut and Alice Wallenberg Foundation
Note
QC 20110421Available from: 2011-04-21 Created: 2011-04-18 Last updated: 2017-12-11Bibliographically approved

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Sun, Licheng

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