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Valence photoionization and the following fragmentation pathways in Sb-4 clusters
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2009 (English)In: Physical Review A. Atomic, Molecular, and Optical Physics, ISSN 1050-2947, E-ISSN 1094-1622, Vol. 80, no 4, 043201- p.Article in journal (Refereed) Published
Abstract [en]

The valence photoelectron spectrum of Sb-4 clusters and the following fragmentation patterns have been studied using synchrotron radiation and electron-ion coincidence technique. An experimental photoelectron spectrum of the 5t(2) ionization of Sb-4 is presented. Theoretical molecular calculations, together with the existing data on the noble gas xenon, were used to describe the experimental results. The bonding properties of the molecular orbitals involved are used to qualitatively describe the dissociation process.

Place, publisher, year, edition, pages
2009. Vol. 80, no 4, 043201- p.
Keyword [en]
antimony, dissociation, molecular clusters, molecular electronic states, molecule-electron collisions, photoelectron spectra, photoionisation
National Category
Atom and Molecular Physics and Optics
Identifiers
URN: urn:nbn:se:kth:diva-32788DOI: 10.1103/PhysRevA.80.043201ISI: 000271351000109Scopus ID: 2-s2.0-70349913921OAI: oai:DiVA.org:kth-32788DiVA: diva2:412954
Note
QC 20110427Available from: 2011-04-27 Created: 2011-04-20 Last updated: 2017-12-11Bibliographically approved

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