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Preparation, characterization and electrochemistry of an iron-only hydrogenase active site model covalently linked to a ruthenium tris(bipyridine) photosensitizer
KTH, School of Chemical Science and Engineering (CHE), Chemistry, Organic Chemistry.ORCID iD: 0000-0002-4521-2870
2008 (English)In: Journal of coordination chemistry (Print), ISSN 0095-8972, Vol. 61, no 12, 1856-1861 p.Article in journal (Refereed) Published
Abstract [en]

An NH2-functionlized [Fe2S2] model complex of the iron-only hydrogenase active site was covalently linked to the tris( bipyridine) ruthenium photosensitizer. The [RuFeFe] trinuclear complex 1 was characterized by MS, IR, UV-vis, H-1 & C-13 NMR spectra. A quasi-reversible reduction peak at - 1.41V versus Ag/Ag+ for the (FeFeI)-Fe-I/(FeFe0)-Fe-I process is observed in the cyclic voltammogram of 1.

Place, publisher, year, edition, pages
2008. Vol. 61, no 12, 1856-1861 p.
Keyword [en]
diiron complex, iron-only hydrogenase, ruthenium photosensitizer, trinuclear complex
National Category
Chemical Sciences
URN: urn:nbn:se:kth:diva-33158DOI: 10.1080/00958970701767002ISI: 000257032300003ScopusID: 2-s2.0-45849102379OAI: diva2:413682
QC 20110429Available from: 2011-04-29 Created: 2011-04-29 Last updated: 2011-04-29Bibliographically approved

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