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Surface-Grafted Conjugated Polymers for Hybrid Cellulose Materials
KTH, School of Chemical Science and Engineering (CHE), Fibre and Polymer Technology.
KTH, School of Chemical Science and Engineering (CHE), Fibre and Polymer Technology.
KTH, School of Chemical Science and Engineering (CHE), Fibre and Polymer Technology.ORCID iD: 0000-0002-8348-2273
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2011 (English)In: Journal of Polymer Science Part A: Polymer Chemistry, ISSN 0887-624X, E-ISSN 1099-0518, Vol. 49, no 14, 3004-3013 p.Article in journal (Refereed) Published
Abstract [en]

Conjugated polymers were grafted onto cellulose substrates in an effort to create a general method for the synthesis of conjugated polymer/cellulose hybrid materials. In this report, we describe the grafting of poly(fluorene), poly(fluorenevinylene), and a poly(fluorene-ethynylene-phenylene) onto modified cellulose paper substrates using Suzuki, Heck, and Sonogashira-type polymerizations, respectively. The application of these three widely used coupling chemistries to surface-grafted conjugated polymers on cellulose provides a general route to cellulose-based hybrid materials tunable with almost any aromatic repeat structure for specific applications.

Place, publisher, year, edition, pages
2011. Vol. 49, no 14, 3004-3013 p.
Keyword [en]
conjugated polymer, graft copolymers, polymer brush, semiconducting polymers, step-growth polymerization, surfaces
National Category
Chemical Sciences
Identifiers
URN: urn:nbn:se:kth:diva-35129DOI: 10.1002/pola.24733ISI: 000291363600002Scopus ID: 2-s2.0-79958230026OAI: oai:DiVA.org:kth-35129DiVA: diva2:426449
Note
QC 20110623Available from: 2011-06-23 Created: 2011-06-20 Last updated: 2017-12-11Bibliographically approved

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Malmström, Eva

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