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The Zr-Sn binary system: New experimental results and thermodynamic assessment
KTH, School of Industrial Engineering and Management (ITM), Materials Science and Engineering.
2008 (English)In: Calphad, ISSN 0364-5916, E-ISSN 1873-2984, Vol. 32, no 3, 593-601 p.Article in journal (Refereed) Published
Abstract [en]

The Zr-Sn binary system has been reinvestigated by several experimental techniques: X-ray diffraction, electron probe micro-analysis, mass density and calorimetry measurements. The existence of a miscibility gap inside the homogeneity domain of the eta phase (Zr5Sn3-Zr5Sn4) has been confirmed. It has been also shown that Zr substitution on the Sn sublattice is responsible for the non-stoichiometry of the A15 phase (Zr4Sn). The temperature of the peritectoid reaction beta(Zr)+A15 alpha(Zr) has been determined to be at 1216 K that is 40 degrees below the temperature reported in the literature. All these new experimental data have been taken into account for a new thermodynamic assessment of this system.

Place, publisher, year, edition, pages
2008. Vol. 32, no 3, 593-601 p.
Keyword [en]
Sn-Zr Binary system, X-ray, Calorimerry, Thermodynamic assessment, Miscibility gap
National Category
Energy Engineering
Identifiers
URN: urn:nbn:se:kth:diva-36431DOI: 10.1016/j.calphad.2008.04.001ISI: 000260324400017Scopus ID: 2-s2.0-51649099979OAI: oai:DiVA.org:kth-36431DiVA: diva2:430795
Note
QC 20110712Available from: 2011-07-12 Created: 2011-07-12 Last updated: 2017-12-11Bibliographically approved

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