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Dissociative recombination study of N-3(+): Cross section and branching fraction measurements
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2007 (English)In: Journal of Chemical Physics, ISSN 0021-9606, E-ISSN 1089-7690, Vol. 127, no 1, 014305- p.Article in journal (Refereed) Published
Abstract [en]

We report an investigation into the dissociative recombination of the azide radical cation, N-3(+). The reaction rate constant has been measured to be 6.47x10(-7) cm(3) s(-1) at room temperature. This value is smaller than those reported earlier for the ion-electron neutralization of N-3(+) at nitrogen atmospheric pressure. A strong propensity to dissociate through the N-2+N channel has been observed.

Place, publisher, year, edition, pages
2007. Vol. 127, no 1, 014305- p.
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Physical Sciences
URN: urn:nbn:se:kth:diva-37327DOI: 10.1063/1.2747601ISI: 000247819800014ScopusID: 2-s2.0-34547829319OAI: diva2:433179
Available from: 2011-08-09 Created: 2011-08-09 Last updated: 2011-08-09Bibliographically approved

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