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SrAlSiH: A polyanionic semiconductor hydride
KTH, School of Information and Communication Technology (ICT), Microelectronics and Information Technology, IMIT.ORCID iD: 0000-0002-9858-6235
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2005 (English)In: Angewandte Chemie International Edition, ISSN 1433-7851, E-ISSN 1521-3773, Vol. 44, no 44, 7269-7273 p.Article in journal (Refereed) Published
Abstract [en]

(Chemical Equation Presented) Stable and semiconducting: Polyanionic hydrides represent a new class of main-group-metal hydrides with unforeseen hydrogen-coordination environments. The hydrogen atom in SrAlSiH is attached exclusively to Al and forms part of a layered [AlHSi]2- polyanion (see figure). This material is the first narrow bandgap semiconductor hydride and combines the high thermal stability of saline hydrides with the air and moisture stability of interstitial transition-metal hydrides.

Place, publisher, year, edition, pages
2005. Vol. 44, no 44, 7269-7273 p.
Keyword [en]
aluminum, hydrides, NMR spectroscopy, semiconductors, zintl phases
National Category
Chemical Sciences
Identifiers
URN: urn:nbn:se:kth:diva-37731DOI: 10.1002/anie.200502090ISI: 000233404500024Scopus ID: 2-s2.0-27844496716OAI: oai:DiVA.org:kth-37731DiVA: diva2:435035
Available from: 2011-08-17 Created: 2011-08-17 Last updated: 2017-12-08Bibliographically approved

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Andersson, Magnus

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