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Dissociative recombination of N2OD+
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2004 (English)In: Physical Chemistry, Chemical Physics - PCCP, ISSN 1463-9076, E-ISSN 1463-9084, Vol. 6, no 13, 3415-3419 p.Article in journal (Refereed) Published
Abstract [en]

Branching ratios and absolute cross sections have been measured for the dissociative recombination of N2OD+ using the CRYRING ion storage ring. The most dominating pathways were found to be those eading to N-2 + OD (46%) and the three-body break-up producing N-2 + O + D (40%). The production of N2O is not observed. The cross section of the reaction could be fitted to the expression sigma = 1.25 +/- 0.25 x 10(-15)(E/eV)(-1.24+/-0.02), which leads to a thermal reaction rate of k(T) = 1.4 +/- 0.1 x 10(-6)(T/300)(-0.74+/-0.02) cm(3) s(-1). The findings are compared with those of the related dissociative recombination of DOCO+ as well as with earlier flowing afterglow measurements.

Place, publisher, year, edition, pages
2004. Vol. 6, no 13, 3415-3419 p.
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Physical Chemistry
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URN: urn:nbn:se:kth:diva-41249DOI: 10.1039/b403461aISI: 000223041400029Scopus ID: 2-s2.0-4043149282OAI: oai:DiVA.org:kth-41249DiVA: diva2:443454
Note
QC 20110926Available from: 2011-09-26 Created: 2011-09-23 Last updated: 2017-12-08Bibliographically approved

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