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Visible light-driven water oxidation-from molecular catalysts to photoelectrochemical cells
KTH, School of Chemical Science and Engineering (CHE), Chemistry, Organic Chemistry.ORCID iD: 0000-0003-1662-5817
KTH, School of Chemical Science and Engineering (CHE), Chemistry, Organic Chemistry.
KTH, School of Chemical Science and Engineering (CHE), Chemistry, Organic Chemistry.
KTH, School of Chemical Science and Engineering (CHE), Chemistry, Organic Chemistry.ORCID iD: 0000-0002-4521-2870
2011 (English)In: Energy & Environmental Science, ISSN 1754-5692, E-ISSN 1754-5706, Vol. 4, no 9, 3296-3313 p.Article in journal (Refereed) Published
Abstract [en]

This perspective article reports the most significant advances in the field of water oxidation-from molecular water oxidation catalysts (WOCs) to photoelectrochemical cells. Different series of catalysts that can be applied in visible light-driven water oxidation catalysis are discussed in details and several key aspects of their catalytic mechanisms are introduced. In order to construct a water oxidation electrode from molecular catalysts, proper immobilization methods have to be employed. Herein, we present one section about how to attach catalysts onto an electrode/material surface. Finally, the state of the art photoelectrochemical cells that achieve visible light-driven water splitting are described.

Place, publisher, year, edition, pages
2011. Vol. 4, no 9, 3296-3313 p.
Keyword [en]
MONONUCLEAR RUTHENIUM COMPLEXES, OXYGEN-EVOLVING CATALYST, TRANSITION-METAL-COMPLEXES, PHOTOSYSTEM-II, ARTIFICIAL PHOTOSYNTHESIS, ELECTROCHEMICAL OXIDATION, IRIDIUM COMPLEXES, CRYSTAL-STRUCTURE, RU(II) COMPLEXES, POLYMER MEMBRANE
National Category
Energy Engineering
Identifiers
URN: urn:nbn:se:kth:diva-41297DOI: 10.1039/c1ee01276bISI: 000294306900014Scopus ID: 2-s2.0-80052214973OAI: oai:DiVA.org:kth-41297DiVA: diva2:444285
Funder
Knut and Alice Wallenberg Foundation
Note
QC 20110928Available from: 2011-09-28 Created: 2011-09-26 Last updated: 2017-12-08Bibliographically approved

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Duan, LeleSun, Licheng

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