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Internal symmetry and selection rules in resonant inelastic soft x-ray scattering
KTH, School of Biotechnology (BIO), Theoretical Chemistry and Biology.
KTH, School of Biotechnology (BIO), Theoretical Chemistry and Biology.ORCID iD: 0000-0003-2729-0290
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2011 (English)In: Journal of Physics B: Atomic, Molecular and Optical Physics, ISSN 0953-4075, E-ISSN 1361-6455, Vol. 44, no 16, 161002- p.Article in journal (Refereed) Published
Abstract [en]

Resonant inelastic soft x-ray scattering spectra excited at the dissociative 1 sigma(g) -> 3 sigma(u) resonance in gas-phase O(2) are presented and discussed in terms of state-of-the-art molecular theory. A new selection rule due to internal spin coupling is established, facilitating a deep analysis of the valence excited final states. Furthermore, it is found that a commonly accepted symmetry selection rule due to orbital parity breaks down, as the core hole and excited electron swap parity, thereby opening the symmetry forbidden 3 sigma(g) decay channel.

Place, publisher, year, edition, pages
2011. Vol. 44, no 16, 161002- p.
Keyword [en]
spectroscopy, excitation
National Category
Atom and Molecular Physics and Optics
Identifiers
URN: urn:nbn:se:kth:diva-41802DOI: 10.1088/0953-4075/44/16/161002ISI: 000294890800002Scopus ID: 2-s2.0-80051700044OAI: oai:DiVA.org:kth-41802DiVA: diva2:445131
Note
QC 20111003Available from: 2011-10-03 Created: 2011-10-03 Last updated: 2017-12-08Bibliographically approved

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Sun, Yu-PingRinkevicius, ZilvinasGelmukhanov, Faris
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