Deviation from local equilibrium
2005 (English)In: Solid-Solid Phase Transformations in Inorganic Material 2005, Vol 2 / [ed] Howe, JM; Laughlin, DE; Lee, JK; Dahmen, U; Soffa, WA, 2005, 327-338 p.Conference paper (Refereed)
In order to learn more about the atomic mechanisms of the migration of phase interfaces one should study the kinetic equations. They are based on the driving forces which can be obtained from the deviation from local equilibrium at the migrating interface. The thermodynamic and mechanistic background of the deviation from local equilibrium will be described and illustrated with molar Gibbs energy diagrams. It will be discussed how the flux equations for individual components can be formulated in order to represent various causes of friction. The discussion will be based on the sharp interface model but its shortcomings will be emphasized.
Place, publisher, year, edition, pages
2005. 327-338 p.
thermodynamics, phase transformation, interface, Gibbs energy dissipation, migration
IdentifiersURN: urn:nbn:se:kth:diva-43335ISI: 000238838100033ScopusID: 2-s2.0-33645214736OAI: oai:DiVA.org:kth-43335DiVA: diva2:448404
International Conference on Solid-Solid Phase Transformations in Inorganic Materials (PTM 2005) Location: Phoenix, AZ Date: MAY 29-JUN 03, 2005
QC 201110172011-10-172011-10-142011-10-17Bibliographically approved