Selenium-molybdenum-based colouration of alkali silicate glasses
2007 (English)In: Glass Technology: European Journal of Glass Science and Technology Part A, ISSN 1753-3546, Vol. 48, no 5, 213-221 p.Article in journal (Refereed) Published
The interaction between selenium and molybdenum in reduced alkali silicate melts, resulting in red glasses has been studied. The oxidation state of Mo is Mo(VI) as evidenced by XANES and ESCA results. Selenium is present in a reduced state, as indicated by ultraviolet/visible spectroscopy and XANES. The colour is described by ultraviolet/visible spectra and CIE colour coordinates. The main absorption peaks are at 450 and 540 nm. Similar bands are reported for MoOSe32-. Several commonly used glass components must be avoided in the batch, as they prevent formation of the red colour.
Place, publisher, year, edition, pages
2007. Vol. 48, no 5, 213-221 p.
IdentifiersURN: urn:nbn:se:kth:diva-46353ISI: 000251516000001ScopusID: 2-s2.0-37149044945OAI: oai:DiVA.org:kth-46353DiVA: diva2:454457
QC 201111072011-11-072011-11-032011-11-07Bibliographically approved