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Selenium-molybdenum-based colouration of alkali silicate glasses
KTH, School of Chemical Science and Engineering (CHE), Chemistry.
2007 (English)In: Glass Technology: European Journal of Glass Science and Technology Part A, ISSN 1753-3546, Vol. 48, no 5, 213-221 p.Article in journal (Refereed) Published
Abstract [en]

The interaction between selenium and molybdenum in reduced alkali silicate melts, resulting in red glasses has been studied. The oxidation state of Mo is Mo(VI) as evidenced by XANES and ESCA results. Selenium is present in a reduced state, as indicated by ultraviolet/visible spectroscopy and XANES. The colour is described by ultraviolet/visible spectra and CIE colour coordinates. The main absorption peaks are at 450 and 540 nm. Similar bands are reported for MoOSe32-. Several commonly used glass components must be avoided in the batch, as they prevent formation of the red colour.

Place, publisher, year, edition, pages
2007. Vol. 48, no 5, 213-221 p.
National Category
Materials Engineering
Identifiers
URN: urn:nbn:se:kth:diva-46353ISI: 000251516000001Scopus ID: 2-s2.0-37149044945OAI: oai:DiVA.org:kth-46353DiVA: diva2:454457
Note
QC 20111107Available from: 2011-11-07 Created: 2011-11-03 Last updated: 2011-11-07Bibliographically approved

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