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Polymer-supported manganese porphyrin catalysts - peptide-linker promoted chemoselectivity
KTH, School of Chemical Science and Engineering (CHE), Chemistry, Organic Chemistry.
2005 (English)In: Organic and biomolecular chemistry, ISSN 1477-0520, E-ISSN 1477-0539, Vol. 3, no 10, 1971-1976 p.Article in journal (Refereed) Published
Abstract [en]

Manganese porphyrin catalysts were tethered to polymer-supports via peptide linkers. The reactivity and chemoselectivity of the catalysts were assessed in the epoxidation of limonene. It was found that the inclusion of a peptide linker incorporating a donor heteroatom which could act as an axial ligand led to a supported manganese porphyrin catalyst with unprecedented selectivity and stability.

Place, publisher, year, edition, pages
2005. Vol. 3, no 10, 1971-1976 p.
Keyword [en]
Amino acids, Manganese compounds, Nuclear magnetic resonance spectroscopy, Oxidation, Polymers, Porphyrins, Synthesis (chemical), Chemoselectivity, Epoxidation, Peptide linkers, Solid phase synthesis
National Category
Organic Chemistry
Identifiers
URN: urn:nbn:se:kth:diva-47283DOI: 10.1039/b502149aISI: 000229067300022Scopus ID: 2-s2.0-19944409380OAI: oai:DiVA.org:kth-47283DiVA: diva2:454606
Note
QC 20111107Available from: 2011-11-07 Created: 2011-11-07 Last updated: 2017-12-08Bibliographically approved

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