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Stereomutation in Trigonal-Bipyramidal Systems: A Unified Picture
KTH, School of Chemical Science and Engineering (CHE), Chemistry, Organic Chemistry.ORCID iD: 0000-0002-1743-7650
2011 (English)In: Angewandte Chemie International Edition, ISSN 1433-7851, E-ISSN 1521-3773, Vol. 50, no 44, 10290-10292 p.Article in journal (Other academic) Published
Abstract [en]

Same difference: Berry pseutorotation (BPR) and Ugi turnstile rotation, which are generally treated as two distinctly different mechanisms for rearrangement of trigonal-bipyramidal structures, have been shown to be equivalent. Alternative mechanisms consist of sequences of pseudorotations proceeding in a single step.

Place, publisher, year, edition, pages
2011. Vol. 50, no 44, 10290-10292 p.
Keyword [en]
fluxionality, phosphorus, pseudorotation, trigonal bipyramids, turnstile rotation
National Category
Chemical Sciences
URN: urn:nbn:se:kth:diva-51299DOI: 10.1002/anie.201103375ISI: 000297049300005ScopusID: 2-s2.0-80055004393OAI: diva2:463855
QC 20111212Available from: 2011-12-12 Created: 2011-12-12 Last updated: 2011-12-12Bibliographically approved

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