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Phase Separation in Melts of the ZrO2–Al2O3 System
St. Petersburg State Institute of Technology (Technical University), Moskovskii pr. 26, St. Petersburg, 198013 Russia.
St. Petersburg State Institute of Technology (Technical University), Moskovskii pr. 26, St. Petersburg, 198013 Russia.
St. Petersburg State Institute of Technology (Technical University), Moskovskii pr. 26, St. Petersburg, 198013 Russia.
St. Petersburg State University of Electrical Engineering, ul. Professora Popova 5, St. Petersburg, 197376 Russia.
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2008 (English)In: Glass Physics and Chemistry, ISSN 1087-6596, E-ISSN 1608-313X, Vol. 34, no 5, 623-633 p.Article in journal (Refereed) Published
Abstract [en]

The morphology of the quenched and slowly crystallized samples in the ZrO2–Al2O3system isinvestigated in the composition range 25–70 wt % ZrO2. It is revealed that, irrespective of the cooling rate, thesamples contain large baddeleyite (or corundum) crystals, eutectic mixtures, and characteristic regions of intergrown elongated baddeleyite and corundum grains with micron sizes. These regions have the same phase composition at any initial ratio between zirconium and aluminum oxides and at any cooling rates of the melt. Ahypothesis is put forward that these regions are products of the decomposition of ZrO2· 2Al2O3associates.

Place, publisher, year, edition, pages
2008. Vol. 34, no 5, 623-633 p.
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Energy Engineering
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URN: urn:nbn:se:kth:diva-63069DOI: 10.1134/S1087659608050143OAI: oai:DiVA.org:kth-63069DiVA: diva2:481588
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QC 20120124

Available from: 2012-01-21 Created: 2012-01-21 Last updated: 2017-06-13Bibliographically approved

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