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Monotectic Crystallization of Melts in the ZrO2–Al2O3 System
St. Petersburg State Technological Institute (Technical University), Moskovskii pr. 26, St. Petersburg, 198013 Russia.
St. Petersburg State Institute of Technology (Technical University), Moskovskii pr. 26, St. Petersburg, 198013 Russia.
St. Petersburg State University of Electrical Engineering, ul. Professora Popova 5, St. Petersburg, 197376 Russia.
St. Petersburg State University of Electrical Engineering, ul. Professora Popova 5, St. Petersburg, 197376 Russia.
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2006 (English)In: Glass Physics and Chemistry, ISSN 1087-6596, E-ISSN 1608-313X, Vol. 32, no 4, 479-485 p.Article in journal (Refereed) Published
Abstract [en]

—The morphology of the crystalline phases prepared at different cooling rates, temperatures, andcompositions of melts in the ZrO2–Al2O3system is investigated. It is established that both the quenched andslowly crystallized samples containing 35–70 wt % ZrO2have a submicron structure. Outside this concentrationrange, the ingots have a zonal structure: the peripheral region is formed by large baddeleyite crystals (at a ZrO2content higher than 70 wt %) or corundum crystals (at a ZrO2content lower than 30 wt %). This character ofthe crystallization confirms the presence of the phase separation (liquid immiscibility) region in melts of thissystem. A variant is proposed for the phase diagram of the system under investigation.

Place, publisher, year, edition, pages
2006. Vol. 32, no 4, 479-485 p.
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Energy Engineering
Identifiers
URN: urn:nbn:se:kth:diva-63071DOI: 10.1134/S1087659606040122ISI: 000240251800012OAI: oai:DiVA.org:kth-63071DiVA: diva2:481591
Note
QC 20120124Available from: 2012-01-21 Created: 2012-01-21 Last updated: 2017-12-08Bibliographically approved

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