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Spectrally and temporarily resolved luminescence study of short-range order in nanostructured amorphous ZrO(2)
KTH, School of Chemical Science and Engineering (CHE), Chemical Engineering and Technology, Chemical Technology.
2011 (English)In: Journal of Applied Physics, ISSN 0021-8979, E-ISSN 1089-7550, Vol. 110, no 10, 103521- p.Article in journal (Refereed) Published
Abstract [en]

The local structure amorphous ZrO(2) doped with europium (Eu(3+)) and its evolution during crystallization was investigated by using spectrally and temporally resolved luminescence of europium. A small contribution of a crystalline, tetragonal-like local phase emission to the overall broad/amorphous emission could be observed in the amorphous state before calcination. Also, a non-negligible amount of amorphous type emission was still detectable with the crystalline europium-doped ZrO(2) obtained on calcination at 500 and 1000 degrees C being assigned to a disordered, monoclinic-like local phase.

Place, publisher, year, edition, pages
2011. Vol. 110, no 10, 103521- p.
National Category
Chemical Engineering
URN: urn:nbn:se:kth:diva-63275DOI: 10.1063/1.3662117ISI: 000297943700056ScopusID: 2-s2.0-82555202648OAI: diva2:483367
QC 20120125Available from: 2012-01-25 Created: 2012-01-23 Last updated: 2012-01-25Bibliographically approved

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