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655-ORGN - Synthesis of highly enantioenriched cyanohydrins by dual Lewis acid - Lewis base activation
KTH, School of Chemical Science and Engineering (CHE), Chemistry, Organic Chemistry.
KTH, School of Chemical Science and Engineering (CHE), Chemistry, Organic Chemistry.
KTH, School of Biotechnology (BIO), Biochemistry.
KTH, School of Biotechnology (BIO), Biochemistry.
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2007 (English)In: Abstract of Papers of the American Chemical Society, ISSN 0065-7727, Vol. 234, 655-ORGN- p.Article in journal (Other academic) Published
Abstract [en]

Enantioenriched acylated cyanohydrins serve as versatile synthons and are themselves important synthetic targets.  By using our efficient catalytic dual Lewis acid - Lewis base activation system, a range of α-ketonitriles were added to both arom. and aliph. aldehydes affording highly enantioenriched O-acylated cyanohydrins in excellent yields.  The reactions proceeded smoothly in only one step with perfect atom economy.  Our recent results as well as the scope and limitations of the system will be presented together with mechanistic aspects.

Place, publisher, year, edition, pages
2007. Vol. 234, 655-ORGN- p.
National Category
Organic Chemistry
Identifiers
URN: urn:nbn:se:kth:diva-71041ISI: 000207594300181OAI: oai:DiVA.org:kth-71041DiVA: diva2:486450
Conference
234th ACS National Meeting, Boston, MA
Note
QC 20120131Available from: 2012-01-30 Created: 2012-01-30 Last updated: 2017-12-08Bibliographically approved

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Moberg, Christina

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