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Rhodium(I) hydrogenation in water: Kinetic studies and the detection of an intermediate using C-13{H-1} PHIPNMR spectroscopy
Lund University.ORCID iD: 0000-0002-1553-4027
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2007 (English)In: Inorganica Chimica Acta, ISSN 0020-1693, E-ISSN 1873-3255, Vol. 360, no 5, 1621-1627 p.Article in journal (Refereed) Published
Abstract [en]

The mechanism for hydrogenation of dimethylmaleate in water using cationic rhodium complexes with water-soluble bi-dentate phosphines has been investigated using kinetics and a novel method for the indirect detection of intermediates in catalytic hydrogenation reactions, whereby a late intermediate was detected. A mechanism is proposed involving fast, irreversible substrate binding followed by a rate-determining reaction with dihydrogen.

Place, publisher, year, edition, pages
2007. Vol. 360, no 5, 1621-1627 p.
Keyword [en]
hydrogenation, rhodium, water-soluble phosphines, mechanism, para-hydrogen, PHIP
National Category
Inorganic Chemistry
Identifiers
URN: urn:nbn:se:kth:diva-48878DOI: 10.1016/j.ica.2006.08.042ISI: 000245772300026OAI: oai:DiVA.org:kth-48878DiVA: diva2:488419
Note
QC 20120202Available from: 2012-02-01 Created: 2011-11-23 Last updated: 2017-12-08Bibliographically approved

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Ahlquist, Mårten

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