Change search
ReferencesLink to record
Permanent link

Direct link
Rhodium(I) hydrogenation in water: Kinetic studies and the detection of an intermediate using C-13{H-1} PHIPNMR spectroscopy
Lund University.ORCID iD: 0000-0002-1553-4027
Show others and affiliations
2007 (English)In: Inorganica Chimica Acta, ISSN 0020-1693, E-ISSN 1873-3255, Vol. 360, no 5, 1621-1627 p.Article in journal (Refereed) Published
Abstract [en]

The mechanism for hydrogenation of dimethylmaleate in water using cationic rhodium complexes with water-soluble bi-dentate phosphines has been investigated using kinetics and a novel method for the indirect detection of intermediates in catalytic hydrogenation reactions, whereby a late intermediate was detected. A mechanism is proposed involving fast, irreversible substrate binding followed by a rate-determining reaction with dihydrogen.

Place, publisher, year, edition, pages
2007. Vol. 360, no 5, 1621-1627 p.
Keyword [en]
hydrogenation, rhodium, water-soluble phosphines, mechanism, para-hydrogen, PHIP
National Category
Inorganic Chemistry
URN: urn:nbn:se:kth:diva-48878DOI: 10.1016/j.ica.2006.08.042ISI: 000245772300026OAI: diva2:488419
QC 20120202Available from: 2012-02-01 Created: 2011-11-23 Last updated: 2012-02-02Bibliographically approved

Open Access in DiVA

No full text

Other links

Publisher's full text

Search in DiVA

By author/editor
Ahlquist, Mårten
In the same journal
Inorganica Chimica Acta
Inorganic Chemistry

Search outside of DiVA

GoogleGoogle Scholar
The number of downloads is the sum of all downloads of full texts. It may include eg previous versions that are now no longer available

Altmetric score

Total: 49 hits
ReferencesLink to record
Permanent link

Direct link