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C-H activation in strongly acidic media. The co-catalytic effect of the reaction medium
California Institute of Technology.ORCID iD: 0000-0002-1553-4027
2009 (English)In: Chemical Communications, ISSN 1359-7345, E-ISSN 1364-548X, no 17, 2373-2375 p.Article in journal (Refereed) Published
Abstract [en]

Quantum mechanical (QM) results are used to establish the role of sulfuric acid solvent in facilitating the reaction between Pt(II)(bpym)Cl(2) (bpym = 2,2'-bipyrimidinyl) and methane; coordination of methane to the platinum catalyst is found to be catalyzed by the acidic medium.

Place, publisher, year, edition, pages
2009. no 17, 2373-2375 p.
Keyword [en]
methane, platinum, platinum complex, pyrimidine derivative, sulfuric acid
National Category
Theoretical Chemistry
Identifiers
URN: urn:nbn:se:kth:diva-48874DOI: 10.1039/b821854dISI: 000265355800035OAI: oai:DiVA.org:kth-48874DiVA: diva2:488424
Note
QC 20120202Available from: 2012-02-01 Created: 2011-11-23 Last updated: 2017-12-08Bibliographically approved

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Ahlquist, Mårten

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