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Structure and Bonding of the Manganese(II) Phosphide Complex (t-BuPH(2))(eta(5)-Cp)Mn{mu-(t-BuPH)}(2)Mn(Cp)(t-BuPH(2))
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2012 (English)In: Organometallics, ISSN 0276-7333, E-ISSN 1520-6041, Vol. 31, no 1, 23-26 p.Article in journal (Refereed) Published
Abstract [en]

Rather than achieving bis-deprotonation of the phosphine, reaction of Cp2Mn (Cp = cyclopentadienyl) with t-BuPH2 at room temperature yields monodeprotonation of half of the available phosphine in the product (t-BuPH2)(η5-Cp)Mn{μ-(t-BuPH)}2Mn(Cp)(t-BuPH2) (1). This complex comprises a Mn(II) phosphide and is a dimer in the solid state, containing a Mn2P2 diamond core. Consistent with the observation of a relatively short intermetal distance of 2.8717(4) Å in 1, DFT analysis of the full structure points to a singlet ground state stabilized by a direct Mn–Mn single bond. This is in line with the diamagnetic character of 1 and an 18-electron count at Mn.

Place, publisher, year, edition, pages
2012. Vol. 31, no 1, 23-26 p.
Keyword [en]
CRYSTAL-STRUCTURES, DIMANGANESE, MN, SUBSTITUTION, CHEMISTRY, LIGANDS, AMIDO, 1ST
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Chemical Sciences
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URN: urn:nbn:se:kth:diva-75574DOI: 10.1021/om200381pISI: 000298897700003Scopus ID: 2-s2.0-84863410051OAI: oai:DiVA.org:kth-75574DiVA: diva2:490616
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QC 20120206

Available from: 2012-02-06 Created: 2012-02-06 Last updated: 2013-04-16Bibliographically approved

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