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A general approach to the covalent immobilization of single polymers
Portland State University.ORCID iD: 0000-0003-1121-4007
2006 (English)In: Angewandte Chemie International Edition, ISSN 1433-7851, E-ISSN 1521-3773, Vol. 45, no 37, 6207-6210 p.Article in journal (Refereed) Published
Abstract [en]

Stuck fast: The covalent immobilization of polymeric single molecules is achieved by the photochemically induced C-H/N-H insertion reaction of perfluorophenylazides (see picture). When the concentration of the surface azido groups is decreased, isolated polymeric single molecules are observed. This technique is especially suited for materials that do not possess functional groups and are difficult to be immobilized by other means. (Chemical Equation Presented).

Place, publisher, year, edition, pages
2006. Vol. 45, no 37, 6207-6210 p.
Keyword [en]
immobilization, photochemistry, polymers, scanning probe microscopy, single-molecule studies
National Category
Chemical Sciences
Identifiers
URN: urn:nbn:se:kth:diva-77365DOI: 10.1002/anie.200602097ISI: 000240815100031PubMedID: 16906617OAI: oai:DiVA.org:kth-77365DiVA: diva2:492027
Note
QC 20120228Available from: 2012-02-07 Created: 2012-02-06 Last updated: 2017-12-08Bibliographically approved

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