Gd silicate: A high-k dielectric compatible with high temperature annealing
2009 (English)In: Journal of Vacuum Science & Technology B, ISSN 1071-1023, E-ISSN 1520-8567, Vol. 27, no 1, 249-252 p.Article in journal (Refereed) Published
The authors report on the investigation of amorphous Gd-based silicates as high-k dielectrics. Two different stacks of amorphous gadolinium oxide (Gd(2)O(3)) and silicon oxide (SiO(2)) on silicon substrates are compared after annealing at temperatures up to 1000 degrees C. Subsequently formed metal oxide semiconductor capacitors show a significant reduction in the capacitance equivalent thicknesses after annealing. Transmission electron microscopy, medium energy ion scattering, and x-ray diffraction analysis reveal distinct structural changes such as consumption of the SiO(2) layer and formation of amorphous Gd silicate. The controlled formation of Gd silicates in this work indicates a route toward high-k dielectrics compatible with conventional, gate first complementary metal-oxide semiconductor integration schemes.
Place, publisher, year, edition, pages
2009. Vol. 27, no 1, 249-252 p.
Annealing; Capacitance; Charge coupled devices; Dielectric materials; Electric conductivity; Gadolinium; Gate dielectrics; Metal analysis; Metallic compounds; MOS devices; Ozone water treatment; Semiconducting silicon; Semiconducting silicon compounds; Semiconductor materials; Silica; Silicates; Silicon compounds; X ray diffraction analysis
IdentifiersURN: urn:nbn:se:kth:diva-50543DOI: 10.1116/1.3025904ISI: 000265839000048OAI: oai:DiVA.org:kth-50543DiVA: diva2:495351
QC 201202092012-02-082011-12-062012-02-09Bibliographically approved