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Modelling of the sulphation of calcined limestone and dolomite—a gas-solid reaction with structural changes in the presence of inert solids
KTH, School of Chemical Science and Engineering (CHE), Chemical Engineering and Technology. (Energiprocesser, Energy Processes)ORCID iD: 0000-0002-0635-7372
KTH, School of Chemical Science and Engineering (CHE), Chemical Engineering and Technology. (Energiprocesser, Energy Processes)
1988 (English)In: Chemical Engineering Science, ISSN 0009-2509, E-ISSN 1873-4405, Vol. 43, no 5, 1183-1193 p.Article in journal (Refereed) Published
Abstract [en]

The partially sintered spheres model is further developed to account for the influence of inert material present in the solid reactant. This model is applicable, for example, to the sulphation of CaO with a variable amount of inert material. An example is the reaction between calcined dolomite, CaO·MgO, and SO2, when used as an SO2 sorbent in a boiler furnace. The results show that the rate of reaction increases and the active part of the sorbent reaches a higher degree of conversion when inert material is present.

Place, publisher, year, edition, pages
1988. Vol. 43, no 5, 1183-1193 p.
National Category
Chemical Engineering
Identifiers
URN: urn:nbn:se:kth:diva-80253DOI: 10.1016/0009-2509(88)85078-4OAI: oai:DiVA.org:kth-80253DiVA: diva2:496144
Note
NR 20140805Available from: 2012-02-09 Created: 2012-02-09 Last updated: 2017-12-07Bibliographically approved

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Publisher's full texthttp://www.sciencedirect.com/science/article/pii/0009250988850784

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Alvfors, Per

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